An all solid state flexible sc prepared through the assembly of nafionfunctionalized reduced graphene oxide rgo thin films and solventcast nafion electrolyte membranes showed a 2fold higher specific capacitance and rate capability compared to those of all solid state graphene scs. Flexible solidstate electrochemical supercapacitors. Allsolidstate flexible supercapacitors based on a carbonmno2 cm coreshell fiber structure were fabricated with high electrochemical performance such as high rate capability with a scan rate up to 20 v s1, high volume capacitance of 2. The charge storage characteristics of a composite nanoarchitecture with a highly functional 3d morphology are reported. Nov 01, 2014 read all solid state flexible microsupercapacitor arrays with patterned graphenemwnt electrodes, carbon on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Pdf graphitic petal electrodes for allsolidstate flexible. Silver nanowire was the excellent electrode material for the transparent, flexible supercapacitor since it has excellent electrical conductivity, transparency, specific area. In this work, a flexible allsolidstate nh4nipo4h2ographene supercapacitor with remarkable performance was successfully assembled. Flexible allsolidstate microsupercapacitor based on ni. These highly flexible and allsolidstate paperlike polymer supercap. Here, we successfully developed a high active area flexible all solid state battery as a model system that consists of thinfilm layers of li4ti5o12, lipon, and lithium deposited on a novel flexible ceramic substrate.
Flexible solidstate supercapacitors are of considerable interest as mobile power supply for future flexible electronics. Transparent, flexible, allsolidstate supercapacitor using. The electrodes are formed by the electropolymerization of aniline monomers into a nanometerthick polyaniline pani film that. The effect of bending in thinfilm batteries is still not well understood. Flexible energy storage devices are essential for the development of.
Although solidstate rgogorgo supercapacitors with unique structures are promising, their moderate capacitance is. The asfabricated flexible allsolidstate planar supercapacitors with nanocoral structures achieve areal capacitance up to 52. Pdf allsolidstate flexible fiberbased mxene supercapacitors. Abstract supercapacitors have attracted enormous attention for energy storage in both academic and industrial sectors in the past years. Graphene networks for highperformance flexible and. Allsolidstate flexible supercapacitors based on a carbonmno 2 cm coreshell fiber structure were fabricated with high electrochemical performance such as high rate capability with a scan rate up to 20 v s 1, high volume capacitance of 2. As one of the energy storage devices, allsolidstate flexible supercapacitors have attracted significant attention because of their high power density, low. The rapid development of flexible and wearable electronics has led to an increase in the demand for flexible supercapacitors with enhanced electrochemical performance.
Mesoporous nh4nipo4h2o for highperformance flexible all. Pdf flexible fibershaped supercapacitors are promising energystorage devices in wearable smart electronics. Supercapacitor containing the pbi2nps in mlg electrodes was. Flexible allsolidstate supercapacitors based on polyaniline orderly. Allsolidstate flexible thinfilm supercapacitors with high. Hana d dawoud 1, talal m altahtamouni 1, moustafa m zagho 1, nasr bensalah 2 1 department of materials science and technology, college of arts and science, qatar university, doha, qatar. Cyclic voltammetry cv curves were obtained in the potential range of 0.
This work proposes a feasible strategy, offering a platform for rational designs of flexible electronics employing a large family of mxenes and their heterostructures as well. Flexible solidstate supercapacitors scs have attracted increasing interest because they can. These devices deliver high specific volumetric capacitance, power density, and energy density, up to. Development and characterization of pbi2 nanoparticles for all. Fiberbased allsolidstate flexible supercapacitors for self. Allsolidstate flexible fiberbased mxene supercapacitors. Flexible all solid state scs based on gp electrolytes have high ionic conductivity and stability, which are composed of a polymer host matrix and a polymer compatible electrolyte 1822. Allsolid state flexible supercapacitors based on graphene. All solid state solutions to energy storage will be intimately integrated into many future devices, including flexible displays, bioimplants, many types of sensors and all electronic. Meanwhile, the allsolidstate flexible supercapacitors based on the symmetric bnhga electrodes demonstrate high specific capacitance 345 mf cm at 1 ma cm and outstanding rate. Highly flexible allsolidstate cabletype supercapacitors. Flexible ultrathin allsolidstate supercapacitors springerlink.
Here we demonstrate a novel kind of ultrathin all solid state supercapacitor configuration with an. Graphene or carbon nanotubes based thin films have been used to fabricate flexible solidstate supercapacitors with high gravimetric specific capacitances 80200 fg, but usually with a rather low overall or areal specific capacitance 350 mfcm2 due to the. Ascs using mno 2 and fe 2 o 3 thin films as positive and negative electrodes, respectively. Highperformance flexible allsolidstate supercapacitor from large freestanding graphenepedotpss films. Jan 19, 2018 flexible and microsized energy conversion storage components are extremely demanding in portable and multifunctional electronic devices, especially those small, flexible, rollup and even wearable ones. Highperformance flexible solid state carbon cloth supercapacitors based on highly processible ngraphene doped polyacrylic acidpolyaniline composites. Allsolidstate flexible supercapacitors based on a carbonmno2 cm coreshell fiber structure were. Asc devices have excellent electrochemical performance with extended potential window of 2. Allgraphene oxide flexible solidstate supercapacitors.
The obtained pani nanotube film could be directly used as a flexible allsolidstate supercapacitor electrode. In this work, we report the fabrication, by electrophoretic deposition epd, of flexible all solid state symmetric high cell potential supercapacitors, comprised of holey reduced graphene oxide. Flexible solidstate supercapacitors based on three. State fiber supercapacitors with an enhanced distributed. Ads classic will be deprecated in may 2019 and retired in october 2019. Symmetric allsolidstate supercapacitor operating at 1.
Nowadays, wearable energy storage devices have been growing rapidly, but flexible systems with both excellent cycling stability and decent flexibility are still challenging. The obtained pani nanotube film could be directly used as a flexible allsolid state supercapacitor electrode. The difference, however, is that solid capacitors contain a solid organic polymer, while electrolytic capacitors use a common liquid electrolyte, hence, the terms solid capacitor versus electrolytic capacitors. Commercial buckypaper bp is a light, flexible, and mechanically robust substrate. Here, we successfully developed a high active area flexible all solid state battery as a model system that consists of thinfilm layers of li 4 ti 5 o 12, lipon, and lithium deposited on a novel flexible ceramic substrate. The flexible ultrathin allsolidstate supercapacitors with good electrochemical and mechanical performance were fabricated by the facile methods. Fabrication of flexible, half printed and allsolidstate. The sing thus, the thickness of a supercapacitor is only 8. Integrated flexible solidstate supercapacitor fabricated in a. Flexible solid state supercapacitors scs have attracted increasing interest because they can. Capacitance effect, small on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. Abstract the practical applications of wearable electronics rely on the successful development of flexible and integrable energy devices with.
Layer structured bismuth selenides bi2se3 and bi3se4 for high. Highperformance flexible allsolidstate supercapacitor from. Furthermore, due to its polymerbased component structure, it has a specific capacitance of as high as 31. Electrospun polymer nanofiber membrane electrodes and an. Nanocarbonbased materials for flexible allsolidstate. Highly flexible and allsolidstate paperlike polymer. Allsolidstate flexible supercapacitors were fabricated using carbon nanotubes cnts, regular office papers, and ionicliquidbased gel electrolytes. Fiberbased allsolidstate flexible supercapacitors for. Gigabyte geeks column of the week all solid capacitor. Highperformance flexible all solid state supercapacitors yusen zhao, yousif alsaid, bowen yao, yucheng zhang, bozhen zhang, neel bhuskute, shuwang wu, and ximin he oriented microstructures are widely found in various biological systems for multiple functions. Woodinspired morphologically tunable aligned hydrogel for. Additionally, the rate capability of the snse 2 nds device was much better than that of the snse ns device, indicating that snse 2 nds are promising active materials for use in highperformance, flexible, all solid state supercapacitors. Allsolidstate flexible supercapacitors fabricated with. An all solid state flexible supercapacitor had been fabricated from bacterial nanocellulose, cnt, and ionic liquidbased gel electrolytes with a good flexibility and mechanical stability kang et al.
In this work, a high scan rate flexible and all solidstate supercapacitor were fabricated using rgo that are decorated via the silver. Flexible, allsolidstate, highcell potential supercapacitors based on holey reduced graphene oxidemanganese dioxide nanosheets article pdf available in electrochimica acta december 2017. Solidstate capacitor said to combine best qualities of. Graphene oxide go and reduced go rgo exhibit several key properties required for supercapacitor components. We demonstrate allsolidstate flexible supercapacitors with high physical flexibility, desirable electrochemical properties, and excellent mechanical integrity, which were realized by rationally exploiting unique properties of bacterial nanocellulose, carbon nanotubes, and ionic liquid based polymer gel electrolytes. Flexible, sandwichlike cntsnico2o4 hybrid paper electrodes for all solid state supercapacitors yongjia zheng1, zhiqiang lin1, wenjun chen1, binghao liang1, huiwei du1, rongliang yang1, xianfeng he1, zikang tang1, 2, xuchun gui1, 1state key lab of optoelectronic materials and technologies, school of electronics and. Highly flexible, all solidstate microsupercapacitors from vertically aligned carbon nanotubes. Highperformance flexible allsolidstate supercapacitor. In conclusion, we have reported a transparent, flexible, allsolidstate supercapacitor that composed of silver nanowire and mno 2. Allsolidstate flexible supercapacitors based on papers. In summary, highly flexible freestanding rgopedotpss films have been successfully prepared and fabricated into flexible all solid state sc devices using pvah 3 po 4 as an electrolyte. Similarly, nonwoven clothes with super rough surfaces have been dipped into a cnt ink to produce the cntcoated clothes. Twodimensional tin selenide nanostructures for flexible all. Layer structured bismuth selenides bi 2se 3 and bi 3se 4 for high energy and.
Bending impact on the performance of a flexible li4ti5o12. Allsolidstate flexible supercapacitors based on papers coated with carbon nanotubes. An all solid state flexible piezoelectric high k film functioning as both a generator and in situ storage unit wangshu ong, t yihe zhang, qian zhang, xinglong luan, engzhu f, leipeng v l liu, and qi an. Nov 20, 2015 highperformance flexible all solid state supercapacitor from large freestanding graphenepedotpss films skip to main content thank you for visiting. Flexible all solid state highpower supercapacitor fabricated with nitrogendoped carbon nanofiber electrode material. And flexible allsolidstate supercapacitor could deliver much higher energy density than conventional capacitors gao et al. In order to get electrical contact of the electrode, the edge of cmgp film was connected with carbon paste tape, which facilities the electrical contact of. Such anisotropic structures provide low tortuosity and. In order to meet the demands for safer energy storage systems to power portable or wearable electronic devices and flexible displays, allsolidstate. Find, read and cite all the research you need on researchgate. A brief overview of flexible cntpani super capacitors. The incorporation of pedotpss and deg into go sheets increased the interlayer spacing of go sheets and prevented the go sheets from restacking, which. Solid capacitors and electrolytic capacitors both store electricity and discharge it when needed.
Pdf highly flexible and allsolidstate paperlike polymer. The fiber super capacitors fscs can be easily integrated into extremely small devices with tiny sizes and various kinds of shapes due to their small volume and high flexibility. Published 9 january 2014 2014 iop publishing ltd nanotechnology, volume 25, number 5. Journal of materials chemistry a case school of engineering. In recent years, much effort have been dedicated to achieve thin, lightweight and even flexible energystorage devices for wearable electronics. The pergobased allsolidstate flexible scs were further engaged to travel their applications in flexible and wearable electronic devices.
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